Radical Telomerization of Olefin with Isocyanide
نویسندگان
چکیده
منابع مشابه
High-Performance Isocyanide Scavengers for Use in Low-Waste Purification of Olefin Metathesis Products
Invited for this month's cover is the group of Karol Grela (University of Warsaw) in collaboration with Apeiron Synthesis (based in the Wrocław Technology Park). The researchers created a new, bidentate isocyanide scavenger that is very effective at removing ruthenium residues from the products of olefin metathesis. The Full Paper itself is available at 10.1002/cssc.201500784.
متن کاملTandem isomerization/telomerization of long chain dienes
The first example of a tandem reaction involving double-bond migration in combination with telomerization is reported. Homogeneous and heterogeneous Ru catalysts were employed as isomerization catalysts, and telomerization was realized using a homogeneous Pd(0) precursor complex with a N-heterocyclic carbene (IMes) ligand. Overall conversions approaching 60% were achieved with the best selectiv...
متن کاملSpectroscopy and Energy Transfer of Molecular Transients: Hydrogen Isocyanide and the Ketenyl Radical
Energy transfer from molecular species has been a long standing topic of profound interest to the chemical physics community. It is worth noting however, that to date, most studies have preferentially focused on chemically stable molecular species. While the literature does contain numerous examples of energy transfer of small radical or chemically unstable species, there have been extremely fe...
متن کاملDirect observation of hexamethylbenzenium radical cations generated during zeolite methanol-to-olefin catalysis: an ESR study.
The generation of hexamethylbenzenium radical cations as the key reaction intermediate in chabazite-type molecular sieve acids (i.e., H-SAPO-34 and H-SSZ-13) during the methanol-to-olefin process has been directly evidenced by ESR spectroscopy.
متن کاملProbabilistic earthquake hazard Analysis with considering Risk-Based concept (Case study of olefin 14)
Background and objective: numerous seismic hazard analysis studies are conducted annually using probabilistic methods throughout the world and Iran, which are usually different from the initial assumptions of analysis or software used. On the other hand, many researches are presented every year about new methods of earthquake hazard zoning, but so far these studies have not computed earthquake ...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Polymer Journal
سال: 1970
ISSN: 0032-3896,1349-0540
DOI: 10.1295/polymj.1.591